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Sections of ternary diagrams rare earths-indium-tin of R(In1−xSnx)3 composition

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Sections of ternary diagrams rare earths-indium-tin of R(In1−xSnx)3 composition

Auteurs : RBID : ISTEX:10973_1988_Article_BF01913193.pdf

Abstract

Results of thermal studies on Nd(In1−xSnx)3 and Gd(In1−xSnx)3 solid solutions are reported, together with those of structural studies on R(In1−xSnx)3 (R=Nd, Sm, Gd, Tb, Dy, Er, Tm). The non linear behaviour of the lattice parameters and the shape of the phase diagrams are compared. The peritectic decomposition of tin-rich phases of Gd(In1−xSnx)3 is pointed out. The necessity of high pressure studies of these solid solutions is outlined.

DOI: 10.1007/BF01913193

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<name>E. A. Franceschi</name>
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<div type="abstract" xml:lang="eng">Results of thermal studies on Nd(In1−xSnx)3 and Gd(In1−xSnx)3 solid solutions are reported, together with those of structural studies on R(In1−xSnx)3 (R=Nd, Sm, Gd, Tb, Dy, Er, Tm). The non linear behaviour of the lattice parameters and the shape of the phase diagrams are compared. The peritectic decomposition of tin-rich phases of Gd(In1−xSnx)3 is pointed out. The necessity of high pressure studies of these solid solutions is outlined.</div>
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<abstract lang="eng">Results of thermal studies on Nd(In1−xSnx)3 and Gd(In1−xSnx)3 solid solutions are reported, together with those of structural studies on R(In1−xSnx)3 (R=Nd, Sm, Gd, Tb, Dy, Er, Tm). The non linear behaviour of the lattice parameters and the shape of the phase diagrams are compared. The peritectic decomposition of tin-rich phases of Gd(In1−xSnx)3 is pointed out. The necessity of high pressure studies of these solid solutions is outlined.</abstract>
<abstract lang="ger">Ergebnisse der thermischen Untersuchung der festen Lösungen Nd(In1−xSnx)3 und Gd(In1−xSnx)3 und der Strukturuntersuchung von R(In1−xSnx)3 (R=Nd, Sm, Gd, Tb, Dy, Er, Tm) werden 'mitgeteilt. Das nichtlineare Verhalten der Gitterparameter und der Verlauf der Phasendiagramme werden verglichen. Die peritektische Zersetzung der zinnreichen Phasen von Gd(In1−xSnx)3 wird erörtert. Auf die Notwendigkeit von Hochdruckuntersuchungen dieser drei festen Lösungen wird hingewiesen.</abstract>
<abstract lang="und">Приведены результат ы термического исследования тверды х растворов Nd(In1−xSnx)3 и Gd(In1−xSnx)3, наряду с резуль татами структурных исследований R(In1−xSnx)3, гд е R=Nd, Sm, Gd, Tb, Dy, Er и Тm. Сопоставлено не линейное поведение параметров решетки и вид фазовых диаграмм. Отмечено пе ритектическое разло жение обогащенных оловом ф аз Gd(In1−xSnx)3. Указано на необходим ость исследования эт их твердых растворов при высоки х давлениях.</abstract>
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<title>Journal of Thermal Analysis</title>
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<title>Journal of thermal analysis</title>
<partNumber>Year: 1988</partNumber>
<partNumber>Volume: 34</partNumber>
<partNumber>Number: 2</partNumber>
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<genre>Archive Journal</genre>
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<dateIssued encoding="w3cdtf">1988-03-01</dateIssued>
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<topic>Chemistry</topic>
<topic>Inorganic Chemistry</topic>
<topic>Physical Chemistry</topic>
<topic>Polymer Sciences</topic>
<topic>Measurement Science, Instrumentation</topic>
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<identifier type="issn">0022-5215</identifier>
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